Efficient Soft-Chemical Synthesis of Large van-der-Waals Crystals of the Room-Temperature Ferromagnet 1T-CrTe2
K.D. Röseler, C. Witteveen, C. Besnard, V. Pomjakushin, H.O. Jeschke, F.O. von Rohr
Preprint arXiv:2408.06239 (abstract)
Ti4Ir2O a time-reversal-invariant fully gapped unconventional superconductor
Debarchan Das, KeYuan Ma, Jan Jaroszynski, Vahid Sazgari, Tomasz Klimczuk, Fabian O von Rohr, Zurab Guguchia
Preprint arXiv:2401.13485v1 (abstract)
Bonding states underpinning structural transitions in IrTe2 observed with micro-ARPES
C.W. Nicholson, M.D. Watson, A. Pulkkinen, M. Rumo, G. Kremer, K.Y. Ma, F.O. von Rohr, C. Cacho, C. Monney
Preprint arXiv:2407.09317 (abstract)
Anomalous Shubnikov-de Haas effect and observation of the Bloch-Grüneisen temperature in the Dirac semimetal ZrTe5
S. Galeski, K. Araki, O.K. Forslund, R. Wawrzynczak, H.F. Legg, P.K. Sivakumar, U. Miniotaite, F. Elson, M. Månsson, C. Witteveen, F.O. von Rohr, A.Q.R. Baron, D. Ishikawa, Q. Li, G. Gu, L.X. Zhao, W.L. Zhu, G.F. Chen, Y. Wang, S.S.P. Parkin, D. Gorbunov, S. Zherlitsyn, B. Vlaar, D.H. Nguyen, S. Paschen, P. Narang, C. Felser, J. Wosnitza, T. Meng, Y. Sassa, S.A. Hartnoll, J. Gooth
Preprint arXiv:2309.10480 (abstract)
Theory of unconventional magnetism in a Cu-based kagome metal
A. Wenger, A. Consiglio, H. Hohmann, M. Dürrnagel, F.O. von Rohr, H.D. Scammell, J. Ingham, D. Di Sante, R. Thomale
Preprint arXiv:2411.03563 (abstract)
Our Publications
Type-II superconductivity in the Dirac semimetal PdTe2
Ritu Gupta, Catherine Witteveen, Debarchan Das, Fabian von Rohr and Rustem Khasanov
Physical review. B 109 13, 134507 (2024)
We report on the microscopic superconducting properties of the Dirac semimetal PdTe2. In this study, we have focused on mosaic crystals of PdTe2, and used detailed zero-field and transverse-field muon-spin relaxation/rotation (μSR), ac-magnetic susceptibility, and resistivity measurements to…
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The Changing Landscape of Materials Discovery
Fabian von Rohr
Chimia 78 12, 855-861 (2024)
In this perspective, we will discuss the impact of some of the most recent advancements in materials discovery, particularly focusing on the role of robotics, artificial intelligence, and self-driving laboratories, as well as their implications for the Swiss research landscape. While it seems…
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Influence of magnetism on vertical hopping transport in CrSBr
Xiaohanwen Lin, Fan Wu, Sara Almudena Lopez Paz, Fabian von Rohr, Marco Gibertini, Ignacio Gutierrez Lezama and Alberto Morpurgo
Physical review research 6 1, 013185 (2024)
We investigate the c -direction conduction in CrSBr in the linear regime, which is not accessible in other van der Waals (vdW) magnetic semiconductors, because of the unmeasurably low current. The resistivity, which is 10 8 − 10 11 times larger than in the a and b directions, exhibits magnetic…
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Ti4Ir2O : A time reversal invariant fully gapped unconventional superconductor
Debarchan Das, KeYuan Ma, Jan Jaroszynski, Vahid Sazgari, Tomasz Klimczuk, Fabian von Rohr and Zurab Guguchia
Physical review. B 110 17, 174507 (2024)
Here we report muon spin rotation ( μ SR ) experiments on the temperature and field dependence of the effective magnetic penetration depth λ ( T ) in the η -carbide-type suboxide Ti 4 Ir 2 O , a superconductor with a considerably high upper critical field. The temperature dependence of λ ( T ) …
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Bonding states underpinning structural transitions in IrTe2 observed with micro-ARPES
C. W. Nicholson, M. D. Watson, A. Pulkkinen, M. Rumo, G. Kremer, K. Y. Ma, Fabian von Rohr, C. Cacho and C. Monney
Physical review. B 110 20, 205123 (2024)
Competing interactions in low-dimensional materials can produce nearly degenerate electronic and structural phases. We investigate structural phase transitions in layered IrTe 2 for which a number of potential transition mechanisms have been postulated. The spatial coexistence of multiple phases…
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Quantum oscillation signatures of the Bloch-Grüneisen temperature in the Dirac semimetal ZrTe5
S. Galeski, K. Araki, O. K. Forslund, R. Wawrzyńczak, H. F. Legg, P. K. Sivakumar, U. Miniotaite, F. Elson, M. Månsson, Catherine Witteveen, Fabian von Rohr, A. Q. R. Baron, D. Ishikawa, Q. Li, G. Gu, L. X. Zhao, W. L. Zhu, G. F. Chen, Y. Wang, S. S. P. Parkin, D. Grobunov, S. Zherlitsyn, B. Vlaar, D. H. Nguyen, S. Paschen, P. Narang, C. Felser, J. Wosnitza, T. Meng, Y. Sassa, S. A. Hartnoll and J. Gooth
Physical review. B 110 12, L121103 (2024)
The electron-phonon interaction is in many ways a solid state equivalent of quantum electrodynamics. Being always present, the e-p coupling is responsible for the intrinsic resistance of metals at finite temperatures, making it one of the most fundamental interactions present in solids. In typical…
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Nonmonotonic superconducting transition temperature and large bulk modulus in the alloy superconductor Nb4Rh2C1−δ
Lifen Shi, Keyuan Ma, Binbin Ruan, Ningning Wang, Jun Hou, Pengfei Shan, Pengtao Yang, Jianping Sun, Genfu Chen, Zhian Ren, Fabian von Rohr, Bosen Wang and Jinguang Cheng
Physical review. B 110 21, 214520 (2024)
We revised normal-state and superconducting properties of an alloy superconductor Nb4Rh2C1−𝛿 through electrical transport, magnetic susceptibility, and specific heat. Our results reveal that it is a Pauli paramagnetic bad metal, a strongly coupled superconductor with specific heat…
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Chemical Principles of Intrinsic Topological Superconductors
Fabian von Rohr
Chemistry of materials 35 22, 9455-9472 (2023)
The concept of topological superconductivity has attracted immense interest in the physics community recently for several reasons: First, topological superconductors represent new phases of matter, which are topologically distinct from any other known phase of matter. Second, their discovery would…
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Competition between magnetic interactions and structural instabilities leading to itinerant frustration in the triangular lattice antiferromagnet LiCrSe2
Elisabetta Nocerino, Shintaro Kobayashi, Catherine Witteveen, Ola K. Forslund, Nami Matsubara, Chiu Tang, Takeshi Matsukawa, Akinori Hoshikawa, Akihiro Koda, Kazuyoshi Yoshimura, Izumi Umegaki, Yasmine Sassa, Fabian von Rohr, Vladimir Pomjakushin, Jess H. Brewer, Jun Sugiyama and Martin Månsson
Communications materials 4 1, 81 (2023)
LiCrSe 2 constitutes a recent valuable addition to the ensemble of two-dimensional triangular lattice antiferromagnets. In this work, we present a comprehensive study of the low temperature nuclear and magnetic structure established in this material. Being subject to a strong…
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Multiple antiferromagnetic phases and magnetic anisotropy in exfoliated CrBr3 multilayers
Fengrui Yao, Volodymyr Multian, Zhe Wang, Nicolas Ubrig, Jérémie Teyssier, Fan Wu, Enrico Giannini, Marco Gibertini, Ignacio Gutierrez Lezama and Alberto Morpurgo
Nature communications 14 1, 4969 (2023)
In twisted two-dimensional (2D) magnets, the stacking dependence of the magnetic exchange interaction can lead to regions of ferromagnetic and antiferromagnetic interlayer order, separated by non-collinear, skyrmion-like spin textures. Recent experimental searches for these textures have focused on …
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Band Gap Opening in Bilayer Graphene-CrCl3/CrBr3/CrI3 van der Waals Interfaces
Giulia Tenasini, David Soler Delgado, Zhe Wang, Fengrui Yao, Dumitru Dumcenco, Enrico Giannini, Kenji Watanabe, Takashi Taniguchi, Christian Moulsdale, Aitor Garcia-Ruiz, Vladimir I. Fal’ko, Ignacio Gutierrez Lezama and Alberto Morpurgo
Nano letters 22 16, 6760-6766 (2022)
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Nuclear and magnetic spin structure of the antiferromagnetic triangular lattice compound LiCrTe2 investigated by μ+SR, neutron and X-ray diffraction
E. Nocerino, Catherine Witteveen, S. Kobayashi, O. K. Forslund, N. Matsubara, A. Zubayer, F. Mazza, S. Kawaguchi, A. Hoshikawa, I. Umegaki, J. Sugiyama, K. Yoshimura, Y. Sassa, Fabian von Rohr and M. Månsson
Scientific reports 12 1, 21657 (2022)
Two-dimensional (2D) triangular lattice antiferromagnets (2D-TLA) often manifest intriguing physical and technological properties, due to the strong interplay between lattice geometry and electronic properties. The recently synthesized 2-dimensional transition metal dichalcogenide LiCrTe $$_2$$ 2 , …
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Dynamic magnetic crossover at the origin of the hidden-order in van der Waals antiferromagnet CrSBr
Sara Almudena Lopez Paz, Zurab Guguchia, Vladimir Y. Pomjakushin, Catherine Witteveen, Antonio Cervellino, Hubertus Luetkens, Nicola Casati, Alberto Morpurgo and Fabian von Rohr
Nature communications 13 1, 4745 (2022)
The van-der-Waals material CrSBr stands out as a promising two-dimensional magnet. Here, we report on its detailed magnetic and structural characteristics. We evidence that it undergoes a transition to an A-type antiferromagnetic state below T N ≈ 140 K with a pronounced…
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Evidence for isotropic s-wave superconductivity in high-entropy alloys
Casey K. W. Leung, Xiaofu Zhang, Fabian von Rohr, Rolf Lortz and Berthold Jäck
Scientific reports 12 1, 12773 (2022)
High-entropy alloys (HEA) form through the random arrangement of five or more chemical elements on a crystalline lattice. Despite the significant amount of resulting compositional disorder, a subset of HEAs enters a superconducting state below critical temperatures, $$T_{\text{c}}
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Resonant Inelastic X-Ray Scattering Study of Electron-Exciton Coupling in High-Tc Cuprates
Francesco Barantani, Michaël Tran, I. Madan, Itzik Kapon, Nimrod Bachar, T. c. Asmara, E. Paris, Y. Tseng, W. Zhang, Y. Hu, Enrico Giannini, G. Gu, T. p. Devereaux, Christophe Berthod, F. Carbone, T. Schmitt and Dirk Van Der Marel
Physical review. X 12 2, 021068 (2022)
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Quasi 1D Electronic Transport in a 2D Magnetic Semiconductor
Fan Wu, Ignacio Gutierrez Lezama, Sara A. Lopéz‐Paz, Marco Gibertini, Kenji Watanabe, Takashi Taniguchi, Fabian Oliver Von Rohr, Nicolas Ubrig and Alberto Morpurgo
Advanced materials, 2109759 (2022)
We investigate electronic transport through exfoliated multilayers of CrSBr, a 2D semiconductor that is attracting attention because of its magnetic properties. We find an extremely pronounced anisotropy that manifests itself in qualitative and quantitative differences of all quantities measured…
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Universal spin-glass behaviour in bulk LaNiO2 , PrNiO2 and NdNiO2
Hai Lin, Dariusz Jakub Gawryluk, Yannick Maximilian Klein, Shangxiong Huangfu, Ekaterina Pomjakushina, Fabian von Rohr and Andreas Schilling
New journal of physics 24 1, 013022 (2022)
Motivated by the recent discovery of superconductivity in infinite-layer nickelate thin films, we report on a synthesis and magnetization study on bulk samples of the parent compounds RNiO2 (R = La, Pr, Nd). The frequency-dependent peaks of the alternating current magnetic…
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Isotope tuning of the superconducting dome of strontium titanate
Willem Rischau, Dorota Pulmannova, Gernot Scheerer, Adrien Stucky, Enrico Giannini and Dirk Van Der Marel
Physical Review Research 4 1, 013019 (2022)
Doped strontium titanate SrTiO3 (STO) is one of the most dilute superconductors known today. The fact that superconductivity occurs at very low carrier concentrations is one of the two reasons that the pairing mechanism is not yet understood, the other being the role played by the proximity to a…
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Uniaxial strain-induced phase transition in the 2D topological semimetal IrTe2
Christopher W. Nicholson, Maxime Rumo, Aki Pulkkinen, Geoffroy Kremer, Björn Salzmann, Marie-Laure Mottas, Baptiste Hildebrand, Thomas Jaouen, Timur K. Kim, Saumya Mukherjee, KeYuan Ma, Matthias Muntwiler, Fabian von Rohr, Cephise Cacho and Claude Monney
Communications materials 2 1, 25 (2021)
Strain is ubiquitous in solid-state materials, but despite its fundamental importance and technological relevance, leveraging externally applied strain to gain control over material properties is still in its infancy. In particular, strain control over the diverse phase transitions and topological…
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Polytypism and superconductivity in the NbS2 system
Catherine Witteveen, Karolina Górnicka, Johan Chang, Martin Månsson, Tomasz Klimczuk and Fabian von Rohr
Dalton transactions 50 9, 3216-3223 (2021)
We report on the phase formation and the superconducting properties in the NbS2 system. Specifically, we have performed a series of standardized solid-state syntheses in this system, which allow us to establish a comprehensive synthesis map for the formation of the two polytypes…
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Charge carrier dynamics and self-trapping on Sb2S3 (100)
Lisa Grad, Fabian von Rohr, Matthias Hengsberger and Jürg Osterwalder
Physical review materials 5 7, 075401 (2021)
Antimony sulfide (Sb2S3) is a promising material for solar energy conversion. It consists of earth-abundant elements with a low toxicity and high stability. Furthermore, it shows suitable optical and electronic properties like a large absorption coefficient and a convenient…
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Ultrafast dynamics of the surface photovoltage in potassium-doped black phosphorus
G. Kremer, M. Rumo, C. Yue, A. Pulkkinen, C. W. Nicholson, T. Jaouen, Fabian von Rohr, P. Werner and C. Monney
Physical review. B 104 3, 035125 (2021)
Black phosphorus is a quasi-two-dimensional layered semiconductor with a narrow direct band gap of 0.3 eV. A giant surface Stark effect can be produced by the potassium doping of black phosphorus, leading to a semiconductor to semimetal phase transition originating from the creation of a strong…
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Two-gap to single-gap superconducting transition on a honeycomb lattice in Ca1−xSrxAlSi
Dorota Iwona Walicka, Zurab Guguchia, Jorge Lago, Olivier Blacque, KeYuan Ma, Huanlong Liu, Rustem Khasanov and Fabian von Rohr
Physical review research 3 3, 033192 (2021)
We report on the structural and microscopic superconducting properties of the Ca1−xSrxAlSi solid solution. Specifically, we have realized the continuous solid solution, which for all members, other than x=0 (CaAlSi), crystallizes in the AlB2-type structure. For CaAlSi, we present an improved…
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Synthetic control over polymorph formation in the d-band semiconductor system FeS2
KeYuan Ma, Robin Lefèvre, Qingtian Li, Jorge Lago, Olivier Blacque, Wanli Yang and Fabian von Rohr
Chemical science 12 41, 13870-13877 (2021)
Pyrite, also known as fool’s gold is the thermodynamic stable polymorph of FeS2. It is widely considered as a promising d-band semiconductor for various applications due to its intriguing physical properties. Marcasite is the other naturally occurring polymorph of FeS2….
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Hydrodynamical description for magneto-transport in the strange metal phase of Bi-2201
Andrea Amoretti, Martina Meinero, Daniel K. Brattan, Federico Caglieris, Enrico Giannini, Marco Affronte, Christian Hess, Bernd Buechner, Nicodemo Magnoli and Marina Putti
Physical review research 2 2, 023387 (2020)
High-temperature superconductors are strongly coupled systems which present a complicated phase diagram with many coexisting phases. This makes it difficult to understand the mechanism which generates their singular transport properties. Hydrodynamics, which mostly relies on the symmetries of the…
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Photoexcited charge carrier dynamics in Sb2Se3 ( 100 )
Lisa Grad, Fabian von Rohr, Jianzhou Zhao, Matthias Hengsberger and Jürg Osterwalder
Physical review materials 4 10, 105404 (2020)
Antimony selenide (Sb2Se3) consists of one-dimensional ribbons that are van der Waals bonded to each other. Due to its favorable optoelectronic properties, it is a promising material for solar energy conversion. Owing to its narrow direct band gap and its high absorption…
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Low-energy excitations in type-II Weyl semimetal Td−MoTe2 evidenced through optical conductivity
D. Santos-Cottin, E. Martino, F. Le Mardelé, Catherine Witteveen, Fabian von Rohr, C. C. Homes, Z. Rukelj and Ana Akrap
Physical review materials 4 2, 021201 (2020)
Molybdenum ditelluride, MoTe2, is a versatile material where the topological phase can be readily tuned by manipulating the associated structural phase transition. The fine details of the band structure of MoTe2, key to understanding its topological properties, have proven…
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Pressure Induced Topological Quantum Phase Transition in Weyl Semimetal Td-MoTe2
Zurab Guguchia, Antonio M. dos Santos, Fabian von Rohr, Jamie J. Molaison, Soham Banerjee, Daniel Rhodes, Jiaxin Yin, Rustem Khasanov, James Hone, Yasutomo J. Uemura, M. Zahid Hasan, Hubertus Luetkens, Emil S. Bozin and Alex Amato
Journal of the Physical Society of Japan 89 9, 094707 (2020)
We report the temperature and pressure (pmax ≃ 1.5 GPa) evolution of the crystal structure of the Weyl semimetal Td-MoTe2 by combination of neutron diffraction and the X-ray total scattering experiments. We find that the fundamental non-centrosymmetric structure…
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Examining the surface phase diagram of IrTe2 with photoemission
M. Rumo, C. W. Nicholson, A. Pulkkinen, B. Hildebrand, G. Kremer, B. Salzmann, M.-L. Mottas, K. Y. Ma, E. L. Wong, M. K. L. Man, K. M. Dani, B. Barbiellini, M. Muntwiler, T. Jaouen, Fabian von Rohr and C. Monney
Physical review. B 101 23, 235120 (2020)
In the transition metal dichalcogenide IrTe2, low-temperature charge-ordered phase transitions involving Ir dimers lead to the occurrence of stripe phases of different periodicities, and nearly degenerate energies. Bulk-sensitive measurements have shown that, upon cooling,…
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Anisotropic character of the metal-to-metal transition in Pr4Ni3O10
Shangxiong Huangfu, Gawryluk Dariusz Jakub, Xiaofu Zhang, Olivier Blacque, Pascal Puphal, Ekaterina Pomjakushina, Fabian von Rohr and Andreas Schilling
Physical review. B 101 10, 104104 (2020)
As a member of the Ruddlesden-Popper Lnn+1NinO3n+1series rare-earth-nickelates, Pr4Ni3O10consists of infinite quasi-two-dimensional perovskite-like Ni-O based layers. Although a metal-to-metal phase transition at Tpt ≈…
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Semimetal-to-semiconductor transition and charge-density-wave suppression in 1T−TiSe2-xSx single crystals
M.-L. Mottas, T. Jaouen, B. Hildebrand, M. Rumo, F. Vanini, E. Razzoli, Enrico Giannini, Céline Barreteau, D. R. Bowler, C. Monney, H. Beck and P. Aebi
Physical review. B 99 15, 155103 (2019)
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Large resistivity reduction in mixed-valent CsAuBr3 under pressure
Pavel Naumov, Shangxiong Huangfu, Xianxin Wu, Andreas Schilling, Ronny Thomale, Claudia Felser, Sergey Medvedev, Harald O. Jeschke and Fabian von Rohr
Physical review. B 100 15, 155113 (2019)
We report on high-pressure p≤45 GPa resistivity measurements on the perovskite-related mixed-valent compound CsAuBr3. The compounds high-pressure resistivity can be classified into three regions: For low pressures (p
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The h-SbxWO3+2x Oxygen Excess Antimony Tungsten Bronze
Fabian von Rohr, Alice Ryser, Huiwen Ji, Karoline Stolze, Jing Tao, Jessica J. Frick, Greta R. Patzke and Robert J. Cava
Chemistry 25 8, 2082-2088 (2019)
We describe the previously unreported oxygen excess hexagonal antimony tungsten bronze with composition Sb0.5W3O10, in the following denoted as h-SbxWO3+2x with x=0.167, to demonstrate its analogy to classical AxWO3…
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Superconductivity in the η-carbide-type oxides Zr4Rh2Ox
KeYuan Ma, Jorge Lago and Fabian von Rohr
Journal of alloys and compounds 796, 287-292 (2019)
We report on the synthesis and the superconductivity in Zr4Rh2Ox (x = 0.4, 0.5, 0.6, 0.7, 1.0). These compounds crystallize in the η-carbide structure, which is a filled version of the complex intermetallic Ti2Ni structure. We find that in the system…
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Superconducting order parameter of the nodal-line semimetal NaAlSi
Lukas Muechler, Zurab Guguchia, Jean-Christophe Orain, Jürgen Nuss, Leslie M. Schoop, Ronny Thomale and Fabian von Rohr
APL materials 7 12, 121103 (2019)
Nodal-line semimetals are topologically nontrivial states of matter featuring band crossings along a closed curve, i.e., nodal-line, in momentum space. Through a detailed analysis of the electronic structure, we show, for the first time, that the normal state of the superconductor NaAlSi, with a…
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Nodeless superconductivity and its evolution with pressure in the layered dirac semimetal 2M-WS2
Zurab Guguchia, Dariusz J. Gawryluk, Marta Brzezinska, Stepan S. Tsirkin, Rustem Khasanov, Ekaterina Pomjakushina, Fabian von Rohr, Joel A. T. Verezhak, M. Zahid Hasan, Titus Neupert, Hubertus Luetkens and Alex Amato
npj quantum materials 4 1, 50 (2019)
Recently, the transition metal dichalcogenide (TMD) system 2M-WS2 has been identified as a Dirac semimetal exhibiting both superconductivity with the highest Tc ~ 8.5 K among all the TMD materials and topological surface states. Here we report on muon spin rotation…
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Unconventional scaling of the superfluid density with the critical temperature in transition metal dichalcogenides
Fabian von Rohr, J.-C. Orain, R. Khasanov, Catherine Witteveen, Z. Shermadini, A. Nikitin, J. Chang, A. R. Wieteska, A. N. Pasupathy, M. Z. Hasan, A. Amato, H. Luetkens, Y. J. Uemura and Z. Guguchia
Science advances 5 11, eaav8465 (2019)
We report on muon spin rotation experiments probing the magnetic penetration depth λ(T) in the layered superconductors in 2H-NbSe2 and 4H-NbSe2. The current results, along with our earlier findings on 1T′-MoTe2 (Guguchia et al.), demonstrate that the superfluid…
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Origin of the pressure-dependent Tc valley in superconducting simple cubic phosphorus
Xianxin Wu, Harald O. Jeschke, Domenico Di Sante, Fabian von Rohr, Robert J. Cava and Ronny Thomale
Physical review materials 2 3, 034802 (2018)
Motivated by recent experiments, we investigate the pressure-dependent electronic structure and electron-phonon (e-ph) coupling for simple cubic phosphorus by performing first-principles calculations within the full potential linearized augmented plane-wave method. As a function of increasing…
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Magnetism in semiconducting molybdenum dichalcogenides
Z. Guguchia, A. Kerelsky, D. Edelberg, S. Banerjee, Fabian von Rohr, D. Scullion, M. Augustin, M. Scully, D. A. Rhodes, Z. Shermadini, H. Luetkens, A. Shengelaya, C. Baines, E. Morenzoni, A. Amato, J. C. Hone, R. Khasanov, S. J. L. Billinge, E. Santos, A. N. Pasupathy and Y. J. Uemura
Science advances 4 12, eaat3672 (2018)
Transition metal dichalcogenides (TMDs) are interesting for understanding the fundamental physics of two-dimensional (2D) materials as well as for applications to many emerging technologies, including spin electronics. Here, we report the discovery of long-range magnetic order below TM = …
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Band Structure of the IV-VI Black Phosphorus Analog and Thermoelectric SnSe
I. Pletikosić, Fabian von Rohr, P. Pervan, P. k. Das, I. Vobornik, R. j. Cava and T. Valla
Physical review letters 120 15, 156403 (2018)
The success of black phosphorus in fast electronic and photonic devices is hindered by its rapid degradation in the presence of oxygen. Orthorhombic tin selenide is a representative of group IV-VI binary compounds that are robust and isoelectronic and share the same structure with black…
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Pressure tuning of structure, superconductivity, and novel magnetic order in the Ce-underdoped electron-doped cuprate T ′−Pr1.3−x La0.7CexCuO4 ( x = 0.1 )
Z. Guguchia, T. Adachi, Z. Shermadini, T. Ohgi, J. Chang, E. S. Bozin, Fabian von Rohr, A. M. dos Santos, J. J. Molaison, R. Boehler, Y. Koike, A. R. Wieteska, B. A. Frandsen, E. Morenzoni, A. Amato, S. J. L. Billinge, Y. J. Uemura and R. Khasanov
Physical review. B 96 9, 094515 (2017)
High-pressure neutron powder diffraction, muon-spin rotation, and magnetization studies of the structural, magnetic, and the superconducting properties of the Ce-underdoped superconducting (SC) electron-doped cuprate system with the Nd2CuO4 (the so-called T′) structure…
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Electron-hole balance and the anomalous pressure-dependent superconductivity in black phosphorus
Jing Guo, Honghong Wang, Fabian von Rohr, Wei Yi, Yazhou Zhou, Zhe Wang, Shu Cai, Shan Zhang, Xiaodong Li, Yanchun Li, Jing Liu, Ke Yang, Aiguo Li, Sheng Jiang, Qi Wu, Tao Xiang, Robert J. Cava and Liling Sun
Physical review. B 96 22, 224513 (2017)
Here we report the in situ high-pressure (up to ∼50-GPa) Hall-effect measurements on single-crystal black phosphorus. We find a strong correlation between the sign of the Hall coefficient, an indicator of the dominant carrier type, and the superconducting transition temperature (Tc)….
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Signatures of the topological s+− superconducting order parameter in the type-II Weyl semimetal Td-MoTe2
Z. Guguchia, Fabian von Rohr, Z. Shermadini, A. T. Lee, S. Banerjee, A. R. Wieteska, C. A. Marianetti, B. A. Frandsen, H. Luetkens, Z. Gong, S. C. Cheung, C. Baines, A. Shengelaya, G. Taniashvili, A. N. Pasupathy, E. Morenzoni, S. J. L. Billinge, A. Amato, R. J. Cava, R. Khasanov and Y. J. Uemura
Nature communications 8 1, 1082 (2017)
In its orthorhombic Td polymorph, MoTe2 is a type-II Weyl semimetal, where the Weyl fermions emerge at the boundary between electron and hole pockets. Non-saturating magnetoresistance and superconductivity were also observed in Td-MoTe2. Understanding the …
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Robust zero resistance in a superconducting high-entropy alloy at pressures up to 190 GPa
Jing Guo, Honghong Wang, Fabian von Rohr, Zhe Wang, Shu Cai, Yazhou Zhou, Ke Yang, Aiguo Li, Sheng Jiang, Qi Wu, Robert J. Cava and Liling Sun
Proceedings of the National Academy of Sciences of the United States of America 114 50, 13144-13147 (2017)
We report the observation of extraordinarily robust zero-resistance superconductivity in the pressurized (TaNb)0.67(HfZrTi)0.33 high-entropy alloy–a material with a body-centered-cubic crystal structure made from five randomly distributed transition-metal elements. The…
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Growth, Crystal Structure and Magnetic Characterization of Zn-Stabilized CePtIn4
Elizabeth M. Carnicom, Tomasz Klimczuk, Fabian von Rohr, Michal J. Winiarski, Tai Kong, Karoline Stolze, Weiwei Xie, Satya K. Kushwaha and Robert J. Cava
Journal of the Physical Society of Japan 86 8, 084710 (2017)
The growth and characterization of CePtIn4, stabilized by 10% Zn substitution for In, is reported. The new material is orthorhombic, space group Cmcm (No. 63), with lattice parameters a = 4.51751(4) Å, b = 16.7570(2) Å, and c = 7.36682(8) Å, and the refined crystal composition has 10% …
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Cobalt complexes of tetradentate, bipyridine-based macrocycles: their structures, properties and photocatalytic proton reduction
E. Joliat, S. Schnidrig, B. Probst, C. Bachmann, B. Spingler, K. K. Baldridge, Fabian von Rohr, A. Schilling and R. Alberto
Dalton transactions 45 4, 1737-1745 (2016)
Complexes with purely pyridine-based macrocycles are rarely studied in photo(electro)catalysis. We synthesized and investigated macrocycles, in which two 2,2′-bipyridine (bpy) units are linked twice by two cyano-methylene groups, to yield the basic tetradentate, bipyridine based ligand framework…
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Direct evidence for a pressure-induced nodal superconducting gap in the Ba0.65Rb0.35Fe2As2 superconductor
Z. Guguchia, A. Amato, J. Kang, H. Luetkens, P. K. Biswas, G. Prando, Fabian von Rohr, Z. Bukowski, A. Shengelaya, H. Keller, E. Morenzoni, Rafael M. Fernandes and R. Khasanov
Nature communications 6, 8863 (2015)
The superconducting gap structure in iron-based high-temperature superconductors (Fe-HTSs) is non-universal. In contrast to other unconventional superconductors, in the Fe-HTSs both d-wave and extended s-wave pairing symmetries are close in energy. Probing the proximity between these very different …
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Superconductivity in rubidium-substituted Ba1−xRbxTi2Sb2O
Fabian von Rohr, Reinhard Nesper and Andreas Schilling
Physical review. B, Condensed matter and materials physics 89 9, 094505 (2014)
We report on the synthesis and the physical properties of Ba1−xRbxTi2Sb2O (x≤0.4) by x-ray diffraction, superconducting quantum interference device magnetometry, resistivity, and specific-heat measurements. Upon hole doping by substituting Ba with Rb, …
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Low-temperature magnetic fluctuations in the Kondo insulator SmB6
P. K. Biswas, Z. Salman, T. Neupert, E. Morenzoni, E. Pomjakushina, Fabian von Rohr, K. Conder, G. Balakrishnan, M. Ciomaga Hatnean, M. R. Lees, D. McK. Paul, A. Schilling, C. Baines, H. Luetkens, R. Khasanov and A. Amato
Physical review. B, Condensed matter and materials physics 89 16, 161107 (2014)
We present the results of a systematic investigation of the magnetic properties of the three-dimensional Kondo topological insulator SmB6 using magnetization and muon-spin relaxation/rotation (μSR) measurements. The μSR measurements exhibit magnetic field fluctuations in…
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Monodisperse Colloidal Gallium Nanoparticles: Synthesis, Low Temperature Crystallization, Surface Plasmon Resonance and Li-Ion Storage
Maksym Yarema, Michael Wörle, Marta D. Rossell, Rolf Erni, Riccarda Caputo, Loredana Protesescu, Kostiantyn V. Kravchyk, Dmitry N. Dirin, Karla Lienau, Fabian von Rohr, Andreas Schilling, Maarten Nachtegaal and Maksym V. Kovalenko
Journal of the American Chemical Society 136 35, 12422-12430 (2014)
We report a facile colloidal synthesis of gallium (Ga) nanoparticles with the mean size tunable in the range of 12-46 nm and with excellent size distribution as small as 7-8%. When stored under ambient conditions, Ga nanoparticles remain stable for months due to the formation of native and…
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Effect of pressure-driven local structural rearrangement on the superconducting properties of FeSe0.5Te0.5
M. Bendele, Z. Guguchia, Fabian von Rohr, T. Irifune, T. Shinmei, I. Kantor, S. Pascarelli, B. Joseph and C. Marini
Physical review. B, Condensed matter and materials physics 90 17, 174505 (2014)
The pressure dependence of the superconducting transition temperature Tc, the local structure, and the electronic properties of the iron chalcogenide superconductor FeSe0.5Te0.5 was investigated by means of SQUID magnetometry and site-selective polarized x-ray absorption…
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Separating the bulk and surface n-to p-type transition in the topological insulator GeBi4−xSbxTe7
Stefan Muff, Fabian von Rohr, Gabriel Landolt, Bartosz Slomski, Andreas Schilling, Robert J. Cava, Jürg Osterwalder and J. Hugo Dil
Physical review. B, Condensed matter and materials physics 88 3, 035407 (2013)
We identify the multilayered compound GeBi4Te7 to be a topological insulator with a Dirac point slightly above the valence band maximum, using angle-resolved photoemission spectroscopy (ARPES) measurements. The spin polarization satisfies the time reversal symmetry of the…
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Conventional superconductivity and charge-density-wave ordering in Ba1−xNaxTi2Sb2O
Fabian von Rohr, Andreas Schilling, Reinhard Nesper, Chris Baines and Markus Bendele
Physical review. B, Condensed matter and materials physics 88 14, 140501 (2013)
We have investigated the low-temperature physical properties of BaTi2Sb2O andBa1−xNaxTi2Sb2O (x = 0.05, 0.1, 0.15, 0.2, 0.25, 0.3) by means of muon spin rotation (μSR) and SQUID magnetometry. Our measurements reveal the absence of …
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Superconductivity and magnetism in RbxFe2−ySe2 : Impact of thermal treatment on mesoscopic phase separation
S. Weyeneth, M. Bendele, Fabian von Rohr, P. Dluzewski, R. Puzniak, A. Krzton-Maziopa, S. Bosma, Z. Guguchia, R. Khasanov, Z. Shermadini, A. Amato, E. Pomjakushina, K. Conder, A. Schilling and H. Keller
Physical review. B, Condensed matter and materials physics 86 13, 134530 (2012)
An extended study of the superconducting and normal-state properties of various as-grown and post-annealed RbxFe2−ySe2 single crystals is presented. Magnetization experiments evidence that annealing of RbxFe2−ySe2 at 413 K, well…
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